Assalam o Alaikum
in this lecture i am going to discuss carboxylation by perkin ring closure reaction with mechanism. This lecture is in urdu ,hindi and english.
main contents of this lecturte are following:-
1) perkin ring closure reaction of carboxylation.
2) perkin ring closure reaction mechanism of carboxylation.
3) carbobylation by perkin ring closure method.
4) decarbobylation by perkin ring closure method.
5)synthesis of cyclopentane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
6)synthesis of cyclobutane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
7)synthesis of cyclopropane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
8)synthesis of cyclohexane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
9)synthesis of cycloheptane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
10)synthesis of cyclooctane-1,1-Dicarboxylic acid by perkin ring closure reaction mechanism.
11)synthesis of carboxylic acid from malonic ester.
12)Reaction of Malonic ester with allkyl halide.
13) caboxylation and decarboxylation
This lecture is delivered in Urdu/hindi/English. This Chemistry Lecture is for FSC BSC And MSC Students who want to prepare this topic in detail and gain 100% marks.
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Assalam o Alaikum in this lecture i am going to discuss the reaction mechanism of the Jones Reagent which is used to oxidized primary alcohols into carboxylic acids and secondary alcohols into ketones. The jones reagent is composed of Chromium Trioxide CrO3, H2O, and H2SO4 (Sulfuric acid) which generates chromic acid H2CrO4. Oxidation of primary alcohols first generates an aldehyde which converts to the geminal / gem diol hydrate form which is then oxidized into a carboxylic acid. Tertiary alcohols are resistant to oxidation.This lecture is delivered in Urdu ,Hindi and English. 1° Alcohols are oxidized to carboxylic acids (RCOOH) under harsher reaction conditions: Na2Cr2O7, K2Cr2O7, or CrO3 in the presence of H2O and H2SO4. The mechanism for the oxidation of 1° alcohols to aldehydes parallels the oxidation of 2° alcohols to ketones detailed is discussed in this lecture. Oxidation of a 1o alcohol to a carboxylic acid requires three operations: oxidation first to the aldehyde, reac
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