Assalam o Alaikum
in this lecture i am going to discuss Baeyer Villiger oxidation mechanism and Rearrangement Reactions & oxidation of aldehyde and ketones to carboxylic acid and ester.This lecture is delivered in Urdu ,Hindi and English.
contents cover:-
1-application of baeyer villiger reaction
2-baeyer villiger oxidation migratory aptitude
3-questions on baeyer villiger oxidation
4-baeyer villiger peracid mechanism
5-asymmetric baeyer villiger
6-baeyer villiger oxidation of enones
7-baeyer villiger oxidation of cyclohexanone
8-Baeyer Villiger oxidation mechanism
9-Rearrangement Reactions
10-oxidation of aldehyde and ketones to carboxylic acid and ester.
11-oxidation of aldehyde to carboxylic acid
12-oxidation of ketones with per acid
13-oxidation of ketones to ester
14-oxidation of aldehydes with per acid
15-organic chemistry by rashid shahzad Baeyer Villiger oxidation mechanism
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This lecture is delivered in Urdu/hindi/English. This Chemistry Lecture is for FSC BSC And MSC Students who want to prepare this topic in detail and gain 100% marks.
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Assalam o Alaikum in this lecture i am going to discuss the reaction mechanism of the Jones Reagent which is used to oxidized primary alcohols into carboxylic acids and secondary alcohols into ketones. The jones reagent is composed of Chromium Trioxide CrO3, H2O, and H2SO4 (Sulfuric acid) which generates chromic acid H2CrO4. Oxidation of primary alcohols first generates an aldehyde which converts to the geminal / gem diol hydrate form which is then oxidized into a carboxylic acid. Tertiary alcohols are resistant to oxidation.This lecture is delivered in Urdu ,Hindi and English. 1° Alcohols are oxidized to carboxylic acids (RCOOH) under harsher reaction conditions: Na2Cr2O7, K2Cr2O7, or CrO3 in the presence of H2O and H2SO4. The mechanism for the oxidation of 1° alcohols to aldehydes parallels the oxidation of 2° alcohols to ketones detailed is discussed in this lecture. Oxidation of a 1o alcohol to a carboxylic acid requires three operations: oxidation first to the aldehyde, reac
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